There is no blood test or scan that can show PMS or PMDD. The diagnosis is made from the pattern of your symptoms.
That is why I often ask you to record your symptoms every day for at least two full menstrual cycles. Looking back, we often remember symptoms differently from how they were. In a diary we can see when the symptoms appear, how strong they are and whether they go away after your period.
Other conditions, for example depression or anxiety, can look like PMS and PMDD or get worse in the days before your period. That is why I look at the whole picture, and finding out whether the symptoms really follow your cycle is an important part of the assessment.